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Pseudorotaxanes with Self-Sorted Sequence and Stereochemistry

C. Talotta, C. Gaeta, Z. Qi, C. A. Schalley, P. Neri – 2013

Partner preferences in pseudorotaxane formation were exploited to establish an integrative self-sorting system able to discriminate simultaneously at the sequence and stereochemical level (see picture). It was found that calix[6]arenes were threaded selectively with a preferred orientation onto bisammonium axles, even when the structural differences between the possible building blocks were small and located remote from the binding sites.

Titel
Pseudorotaxanes with Self-Sorted Sequence and Stereochemistry
Verfasser
C. Talotta, C. Gaeta, Z. Qi, C. A. Schalley, P. Neri
Datum
2013-06-05
Kennung
DOI 10.1002/anie.201301570, 10.1002/ange.201301570
Zitierweise
Angew. Chem. Int. Ed. 2013, 52, 7437-7441; Angew. Chem. 2013, 125, 7585-7589
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